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Basic Volume
Surface Active Agent
Properties of Emulsifier
Functions of Emulsifier
Application Volume
Kind of Emulsifiers
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An
emulsifier consists of water soluble hydrophilic parts and water-insoluble,
oil-soluble lipophilic parts within its.
When an emulsifier is added to a mixture of water and oil, the emulsifier
is arranged on the interface, anchoring its hydrophilic part into water
and its lipophilic part into oil.
On
the interface surface of water and air and of oil and air, the hydrophilic
part and the lipophilic part are adsorbed and arranged around the interface.
The interfacial tension is reduced by the emulsifier.
That is, the force to separate the oil and water is thus weakened, resulting
in the easily mixing of oil and water.
HLB
The hydrophilicity and lipophilicity are different among emulsifiers,
and the balance between the two is called HLB value. The value ranges
from 0 to 20.
An emulsifier with higher lipophilicity shows a lower HLB whereas higher
hydrophilicity has high HLB, and the behaviors and functions to water
depend on this HLB.
| Characteristic behaviors related to water |
HLB |
ratio |
functions |
| hydrophilic
part |
lipophilic
part |
| not dispersing |
0 |
0 |
100 |
|
| |
anti-foaming
agent |
|
| slightly dispersing |
2 |
10 |
90 |
| |
| 4 |
20 |
80 |
|
W/O
emulsification |
| |
| 6 |
30 |
70 |
| |
wetting
agent |
|
| milky dispersion |
8 |
40 |
60 |
O/W
emulsification |
| |
| stable milky dispersion |
10 |
50 |
50 |
|
| |
| transparent dispersion |
12 |
60 |
40 |
| |
cleaning
agent |
| colloidal solution |
14 |
70 |
30 |
| |
| 16 |
80 |
20 |
solubilizing
agent |
| |
| 18 |
90 |
10 |
| |
|
| 20 |
100 |
0 |
All
compounds that have hydrophilic parts and lipophilic parts are not always
useable as an emulsifier. when hydrophilicity is too great, such compounds
disperse into water and the ones with great lipophilicity would disperse
into oil.
When the hydrophilicity and lipophilicity are well-balanced, the emulsifier
exhibits sufficient effects.
| type |
|
W/O |
|
O/W |
|
| HLB |
1 |
2 |
3 |
4 |
5 |
6 |
7 |
8 |
9 |
0 |
1 |
2 |
3 |
4 |
5 |
6 |
7 |
8 |
9 |
0 |
| Monoglycerides |
3~4 |
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| Acetylated monoglycerides |
1 |
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| Lactylated monoglycerides |
3~4 |
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| Citlated monoglycerides |
9 |
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| Succinylated monoglycerides |
5~7 |
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| DATEM |
8~10 |
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| Polyglycerol esters |
1~14 |
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| Sucrose esters |
1~16 |
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| Sorbitan esters |
2~9 |
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| CSL, SSL |
7~9 |
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| Lecithin |
3~4 |
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